Decarbonylative Aryl Thioether Synthesis by Ni Catalysis
化学
硫醚
芳基
催化作用
脱碳
镍
组合化学
有机化学
烷基
作者
Kota Ishitobi,Ryota Isshiki,Kitty K. Asahara,Cassandra Lim,Kei Muto,Junichiro Yamaguchi
出处
期刊：Chemistry Letters [The Chemical Society of Japan] 日期：2018-04-06卷期号：47 (6): 756-759被引量：46
标识
DOI：10.1246/cl.180226
摘要
A decarbonylative aryl thioether synthesis by nickel catalysis is described. After optimization of the reaction conditions, two air-stable Ni catalytic systems [Ni(OAc)2/PnBu3 and Ni(OAc)2/dppb] were identified. Using these catalysts, various aryl thioesters can be converted to the corresponding aryl thioethers in decarbonylative fashion.
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