发光
光致发光
胺气处理
结晶学
离子
配位聚合物
聚合物
晶体结构
特里斯
材料科学
化学
紫外线
光电子学
有机化学
生物化学
作者
Zhangjing Zhang,Yingjun Zhang,Cheng Wang,Lirong Cai,Yutao Xie,Genqiang Xue
标识
DOI:10.1016/j.inoche.2006.01.026
摘要
A new photoluminescent heterobimetallic Zn(II)–Ag(I) cyano-bridged coordination polymer, [Ag5Zn2(tren)2(CN)9] (tren = tris(2-aminoethyl)amine) (1), has been synthesized and structurally characterized. It features rare linear pentameric unit of dicyanoargentate(I) ions assembled by d10–d10 interaction as building blocks. Solid state emission spectrum of 1 shows strong ultraviolet luminescence with emission peak in the range of 376 nm.
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