废止
部分
铑
化学
亲核细胞
催化作用
劈理(地质)
铜
亲核加成
键裂
炔烃
过渡金属
组合化学
药物化学
立体化学
有机化学
材料科学
断裂(地质)
复合材料
作者
Bi‐Jie Li,Hao‐Yuan Wang,Qilei Zhu,Zhang‐Jie Shi
标识
DOI:10.1002/anie.201200271
摘要
Doubled up: A rhodium(III)/copper(II) system co-catalyzes the annulation of benzimides with internal alkynes for the synthesis of indenones (see scheme; Cp*=C5Me5). The reaction involves an uncommon nucleophilic addition of a transition-metal–carbon bond to an imide moiety. This novel reaction provides a facile route to synthesize indenones from readily available benzimides and internal alkynes.
科研通智能强力驱动
Strongly Powered by AbleSci AI