镁
电解质
快离子导体
金属
无机化学
材料科学
离子电导率
金属转移
离子键合
化学
离子
冶金
电极
有机化学
物理化学
催化作用
作者
Michael L. Aubrey,Rob Ameloot,Brian M. Wiers,Jeffrey R. Long
摘要
A series of solid magnesium electrolytes were synthesized via the transmetallation of magnesium phenolates to coordinatively unsaturated metal sites lining the pores of the metal–organic frameworks Mg2(2,5-dioxidobenzene-1,4-dicarboxylate) and Mg2(4,4′-dioxidobiphenyl-3,3′-dicarboxylate). The resulting materials represent a new class of solid magnesium electrolytes that are both crystalline, and exhibit room-temperature ionic conductivities up to 0.25 mS cm−1. The materials reported herein are one-hundred times more conductive at room temperature than any other solid magnesium electrolyte and represent the only class of materials sufficiently conductive for practical consideration in magnesium batteries.
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