电解质
阳极
镁
阴极
电池(电)
硫黄
材料科学
储能
无机化学
化学工程
极化(电化学)
电化学
化学
电极
冶金
物理
物理化学
功率(物理)
量子力学
工程类
作者
Zhirong Zhao‐Karger,Runyu Liu,Wenxu Dai,Zhenyou Li,Thomas Diemant,Bhaghavathi P. Vinayan,Christian Bonatto Minella,Xingwen Yu,Arumugam Manthiram,R. Jürgen Behm,Mario Ruben,Maximilian Fichtner
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2018-07-25
卷期号:3 (8): 2005-2013
被引量:255
标识
DOI:10.1021/acsenergylett.8b01061
摘要
The rechargeable magnesium (Mg) battery has been considered a promising candidate for future battery generations due to unique advantages of the Mg metal anode. The combination of Mg with a sulfur cathode is one of the attractive electrochemical energy storage systems that use safe, low-cost, and sustainable materials and could potentially provide a high energy density. To develop a suitable electrolyte remains the key challenge for realization of a magnesium sulfur (Mg–S) battery. Herein, we demonstrate that magnesium tetrakis(hexafluoroisopropyloxy) borate Mg[B(hfip)4]2 (hfip = OC(H)(CF3)2) satisfies a multitude of requirements for an efficient and practical electrolyte, including high anodic stability (>4.5 V), high ionic conductivity (∼11 mS cm–1), and excellent long-term Mg cycling stability with a low polarization. Insightful mechanistic studies verify the reversible redox processes of Mg–S chemistry by utilizing Mg[B(hfip)4]2 electroylte and also unveil the origin of the voltage hysteresis in Mg–S batteries.
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