材料科学
阳极
尖晶石
电化学
钠
离子
电池(电)
结晶度
钠离子电池
电压
储能
化学工程
电极
物理化学
电气工程
复合材料
热力学
冶金
物理
工程类
法拉第效率
功率(物理)
化学
量子力学
作者
Qi Li,Kezhu Jiang,Xiang Li,Yu Qiao,Xiaoyu Zhang,Ping He,Shaohua Guo,Haoshen Zhou
标识
DOI:10.1002/aenm.201801162
摘要
Abstract Sodium‐ion batteries with abundant and low‐cost sodium resources is a promising alternative to Li‐ion batteries in large‐scale energy applications. While the anode materials, due to their insufficient cycling life and insecure voltage, could not still satisfy the market demands, especially in the wide‐temperature fields, here, a high‐crystallinity anode material with post‐spinel structure, namely NaV 1.25 Ti 0.75 O 4 , which always maintains excellent electrochemical performance at the widely variable temperatures, is reported. The results indicate that this anode delivers a high‐safety and ultrastable room‐temperature performance (i.e., an average output voltage of 0.7 V vs Na + /Na and the ultralong cycling life over 10 000 cycles) and good wide‐temperature performance (below 9% capacity variation at 60 and −20 °C compared to that at 25 °C). These excellent achievements could benefit from the long durability and stability of 1D channels and superfast ion diffusion in a temperature‐dependent range. This finding provides a promising strategy to construct the safe and stable full‐cell prototypes and promotes the wide‐temperature application of sodium‐ion batteries.
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