催化作用
法拉第效率
氨生产
可逆氢电极
材料科学
氨
氧化还原
无机化学
产量(工程)
氢
过渡金属
贵金属
电化学
金属
氮气
电极
化学
物理化学
工作电极
有机化学
冶金
作者
Ling Zhang,Xuqiang Ji,Xiang Ren,Yongjun Ma,Xifeng Shi,Ziqi Tian,Abdullah M. Asiri,Liang Chen,Bo Tang,Xuping Sun
标识
DOI:10.1002/adma.201800191
摘要
Abstract The discovery of stable and noble‐metal‐free catalysts toward efficient electrochemical reduction of nitrogen (N 2 ) to ammonia (NH 3 ) is highly desired and significantly critical for the earth nitrogen cycle. Here, based on the theoretical predictions, MoS 2 is first utilized to catalyze the N 2 reduction reaction (NRR) under room temperature and atmospheric pressure. Electrochemical tests reveal that such catalyst achieves a high Faradaic efficiency (1.17%) and NH 3 yield (8.08 × 10 −11 mol s −1 cm −1 ) at −0.5 V versus reversible hydrogen electrode in 0.1 m Na 2 SO 4 . Even in acidic conditions, where strong hydrogen evolution reaction occurs, MoS 2 is still active for the NRR. This work represents an important addition to the growing family of transition‐metal‐based catalysts with advanced performance in NRR.
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