We experimentally demonstrate a high-spectral-purity photon source by designing a dual-Mach–Zehnder-interferometer-coupled silicon ring resonator, wherein the linewidths of pump and signal (idler) resonances can be engineered independently. A high spectral purity of 95%±1.5% is obtained via a time-integrated g(2) correlation measurement, which exceeds the theoretical 93% bound of a traditional ring’s spontaneous four-wave-mixing photon source. This source also possesses high performance in other metrics including a measured coincidence of 9599 pairs/s and a preparation heralding efficiency of 52.4% at a relatively low pump power of 61 µW as well as high drop-to-through suppression of 20.2 dB. By overcoming the trade-off between spectral purity and brightness in the post-filtering way, such a method guarantees bright pure photons and will pave the way for development of on-chip quantum information processing with improved operation fidelity and efficiency.