莲花效应
材料科学
各向异性
各向同性
接触角
纳米技术
极化(电化学)
复合材料
光学
化学
原材料
有机化学
物理
物理化学
作者
Fei Gao,Yuan Yao,Wei Wang,Xiaofan Wang,Lei Li,Qixin Zhuang,Shaoliang Lin
出处
期刊:Macromolecules
[American Chemical Society]
日期:2018-03-30
卷期号:51 (7): 2742-2749
被引量:62
标识
DOI:10.1021/acs.macromol.8b00059
摘要
Light-driven transformation from isotropic superhydrophobicity to anisotropic superhydrophobicity was accomplished through bio-inspired modification and reconfiguration on poly[6-(4-methoxy-4′-oxyazobenzene)hexyl methacrylate] (PAzoMA) microarrays. In this study, ordered PAzoMA microarray film was fabricated via the reverse breath figure (RBF) method. After gold nanoparticles sputtering and subsequent modification with self-assembly of 1H,1H,2H,2H-perfluorodecanethiol (FSH), the obtained lotus-leaf-inspired film showed isotropic superhydrophobicity with self-cleaning property due to the hierarchical structure and low surface free energy. Upon irradiation with linearly polarized light (LPL), the microspheres were elongated along the direction of polarization and exhibited anisotropic superhydrophobicity resembling rice leaf. With the increase of illumination time, the axis ratio became larger, and anisotropy sliding was more obvious. This research enriches responsive bio-inspired superhydrophobicity and further provides a promising candidate for smart water harvesting.
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