佩多:嘘
材料科学
阳极
微生物燃料电池
塔菲尔方程
介电谱
电极
循环伏安法
化学工程
聚(3,4-亚乙基二氧噻吩)
电化学
阴极
润湿
复合材料
聚合物
化学
物理化学
工程类
作者
Qian Ma,Kai‐Bo Pu,Wenfang Cai,Yun‐Hai Wang,Qing‐Yun Chen,Fujun Li
标识
DOI:10.1021/acs.iecr.8b00563
摘要
Poly(3,4-ethylenedioxythiophene) (PEDOT) was electrochemically polymerized to in situ modify stainless steel (SS) plate electrode to improve its microbial bioelectrocatalytic activity as high-performance anode in microbial fuel cells. After modification, the surface of the electrode became rougher and showed better wettability. The electrochemical characteristics of PEDOT modified SS (PEDOT/SS) and bare SS electrodes were studied by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and Tafel corrosion polarization curves, respectively. It has been demonstrated that PEDOT modification could increase electrode capacitance and reduce electron transfer resistances. Compared with untreated SS, PEDOT/SS electrode showed better anticorrosion property as well. The modified anode produced a maximum power density of 608.6 mW/m2, which was about 6 times higher than bare SS anode. These results indicate that PEDOT treatment is an efficient method for SS to improve its performance as anode in MFCs.
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