Lawsonia inermis mediated synthesis of ZnO/Fe2O3 nanorods for photocatalysis – Biological treatment for the enhanced effluent treatment, antibacterial and antioxidant activities

纳米棒 光催化 流出物 抗氧化剂 莱索尼亚 抗菌活性 化学 核化学 纳米技术 材料科学 传统医学 细菌 催化作用 生物化学 医学 生物 环境科学 环境工程 遗传学
作者
Suganthi Nachimuthu,S. Thangavel,Karthik Kannan,S. Vijayalakshmi,Karnan Muthusamy,Masoom Raza Siddiqui,Saikh Mohammad Wabaidur,C. Parvathiraja
出处
期刊:Chemical Physics Letters [Elsevier]
卷期号:804: 139907-139907 被引量:40
标识
DOI:10.1016/j.cplett.2022.139907
摘要

• The combination of photocatalytic degradation, with biological treatment of bio enzyme with photocatalysts such as LI-ZnO and LI-ZnO/Fe 2 O 3 nanorods. • Lawsonia inermis leaves extract was act as a capping agent for synthesis of the samples. • The synthesized nanorods are characterized using XRD, FT-IR, UV–Visible, and fluorescence. • The efficiency of the treatment was assessed through the decrease in the intermediate product and which was confirmed through HPLC studies. • The enhanced degradation of effluent with 98% efficiency was accomplished on the five days post-treated LI-ZnO/Fe 2 O 3 /H 2 O 2 on the biological degradation process. The major objective of this report is to inspect the combination of photocatalytic degradation, with biological treatment of bio enzyme with photocatalysts such as LI-ZnO and LI-ZnO/Fe 2 O 3 nanorods and Lawsonia inermis leaves extract was act as a capping agent for synthesis of the samples. The synthesized nanorods were characterized using XRD, FT-IR, UV–Visible, and fluorescence. LI-ZnO/Fe 2 O 3 nanorods have lower charge carrier recombination and charge transfer resistance than LI-ZnO nanorods. Photocatalytic degradation was done with LI-ZnO and LI-ZnO/Fe 2 O 3 , in the presence of H 2 O 2 and bio enzyme. Coupling of bio enzyme with LI-ZnO and LI-ZnO/Fe 2 O 3 showed a negative synergetic effect due to the rapid inactivation of bio enzyme. However, the biological treatment was more effective than only bio enzyme used in the post-treatment of photocatalytic treated effluent. The efficiency of the treatment was assessed through the decrease in the intermediate product and which was confirmed through HPLC studies. Moreover, the enhanced degradation of effluent with 98% efficiency was accomplished on the five days post-treated LI-ZnO/Fe 2 O 3 /H 2 O 2 on the biological degradation process.
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