电解
电解质
储能
水溶液
氧化还原
电极
电解水
化学
电化学
纳米技术
化学工程
无机化学
材料科学
有机化学
物理
物理化学
功率(物理)
量子力学
工程类
作者
Jianhang Huang,Xiaoli Dong,Zhaowei Guo,Yonggang Wang
标识
DOI:10.1002/anie.202003198
摘要
Abstract Aqueous batteries using inorganic compounds as electrode materials are considered a promising solution for grid‐scale energy storage, while wide application is limited by the short life and/or high cost of electrodes. Organics with carbonyl groups are being investigated as the alternative to inorganic electrode materials because they offer the advantages of tunable structures, renewability, and they are environmentally benign. Furthermore, the wide internal space of such organic materials enables flexible storage of various charged ions (for example, H + , Li + , Na + , K + , Zn 2+ , Mg 2+ , and Ca 2+ , and so on). We offer a comprehensive overview of the progress of organics containing carbonyls for energy storage and conversion in aqueous electrolytes, including applications in aqueous batteries as solid‐state electrodes, in flow batteries as soluble redox species, and in water electrolysis as redox buffer electrodes. The advantages of organic electrodes are summarized, with a discussion of the challenges remaining for their practical application.
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