Investigation of electrically conductive acrylonitrile‐butadiene rubber

Abstract Electrically conductive acrylonitrile‐butadiene rubbers (NBRs) containing carbon black (CB) as conductive filler were prepared in order to investigate their electrical and mechanical properties. The effects of conductive CB loading, temperature, acrylonitrile content, crosslinking density of vulcanizates, and plasticizer on conductivity were studied. The change in electrical conductivity of NBRs with different amounts of CB showed that there is a certain critical point (percolation threshold) where a significant decrease in electrical resistivity (increase in conductivity) is observed. Mechanical properties such as tensile strength, elongation to break, and surface hardness of vulcanized NBRs were measured. It was found that the percolation threshold was 5 phr of CB for the NBR/CB composites. J. VINYL ADDIT. TECHNOL., 13:71–75, 2007. © 2007 Society of Plastics Engineers.