Azodicarbonamide and sodium bicarbonate blends as blowing agents for crosslinked polyethylene foam

材料科学 化学工程 发泡剂 发泡剂 聚乙烯 碳酸氢钠 复合材料
作者
G. L. A. Sims,W Sirithongtaworn
出处
期刊:Cellular Polymers [SAGE Publishing]
卷期号:16 (4): 271-283 被引量:1
链接
摘要

Thermal decomposition characteristics of chemical blowing agent systems comprising of commercially available blowing agents based on azodicarbonamide and sodium bicarbonate were investigated. After characterising the blowing agent systems and postulating possible reaction mechanisms, they were compounded into a crosslinked polyethylene foam formulation and expanded using compression moulding variations or at atmospheric pressure. Density and in-mould temperature profiles were interpreted in the light of blowing agent system properties, detailed process parameters and permeability of individual gaseous decomposition products through polyethylene. It was concluded that as the bicarbonate proportion increased in the ADC/bicarbonate system, the higher carbon dioxide concentration in the decomposition gases tended to diffuse through the system (and potentially out of the foam) resulting in lower foaming efficiency. It was shown that systems incorporating sodium bicarbonate were entirely unsuitable for continuous atmospheric foaming of chemically crosslinked LDPE foams due to gaseous products being liberated prior to a sufficient build up of crosslinking. Conversely, processing the same formulations by compression moulding techniques produced similar densities (using equal proportions of sodium bicarbonate and azodicarbonamide) under appropriate process conditions. The advantage was a significantly reduced exotherm than that obtained with pure or activated azodicarbonamide. This would appear to suggest advantages in processing more highly temperature sensitive foams such as those based on ethylene copolymers or the even more stringent requirements for minimal heat build-up PVC foaming. Optimisation of foaming efficiency seemed to lie in investigation of modifying the diffusion rate of carbon dioxide through nonpolar polymers.

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
bkagyin应助牛牛采纳,获得10
1秒前
Luo发布了新的文献求助10
1秒前
2秒前
4秒前
xiaozhuzhu完成签到,获得积分10
7秒前
nihaoxjm发布了新的文献求助10
7秒前
亦玉完成签到,获得积分10
8秒前
无聊的南松完成签到,获得积分10
9秒前
10秒前
Orange应助古月采纳,获得10
11秒前
11秒前
悦耳的咖啡豆完成签到,获得积分10
14秒前
dingz完成签到,获得积分10
14秒前
领导范儿应助怡然小蚂蚁采纳,获得10
15秒前
16秒前
共享精神应助金金钟采纳,获得30
16秒前
严念桃完成签到,获得积分10
17秒前
SYLH应助Bob采纳,获得10
19秒前
昏睡的汉堡完成签到,获得积分10
19秒前
FashionBoy应助m0405采纳,获得10
19秒前
虚心的飞雪完成签到,获得积分10
20秒前
ding应助月亮不睡我不睡采纳,获得10
20秒前
20秒前
优秀笑寒完成签到,获得积分10
21秒前
CipherSage应助古月采纳,获得10
22秒前
24秒前
24秒前
梓亮发布了新的文献求助10
26秒前
Zsilu完成签到,获得积分10
26秒前
易槐完成签到,获得积分10
28秒前
29秒前
29秒前
金金钟发布了新的文献求助30
30秒前
30秒前
桐桐应助火星上的听云采纳,获得10
30秒前
31秒前
Bob完成签到,获得积分10
31秒前
李萌萌完成签到 ,获得积分10
32秒前
Tao完成签到 ,获得积分10
33秒前
别管我了应助研友_kngjrL采纳,获得10
33秒前
高分求助中
The Mother of All Tableaux Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 2400
Ophthalmic Equipment Market by Devices(surgical: vitreorentinal,IOLs,OVDs,contact lens,RGP lens,backflush,diagnostic&monitoring:OCT,actorefractor,keratometer,tonometer,ophthalmoscpe,OVD), End User,Buying Criteria-Global Forecast to2029 2000
Cognitive Neuroscience: The Biology of the Mind 1000
Cognitive Neuroscience: The Biology of the Mind (Sixth Edition) 1000
Optimal Transport: A Comprehensive Introduction to Modeling, Analysis, Simulation, Applications 800
Official Methods of Analysis of AOAC INTERNATIONAL 600
ACSM’s Guidelines for Exercise Testing and Prescription, 12th edition 588
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 3958225
求助须知:如何正确求助?哪些是违规求助? 3504388
关于积分的说明 11118283
捐赠科研通 3235682
什么是DOI,文献DOI怎么找? 1788411
邀请新用户注册赠送积分活动 871211
科研通“疑难数据库(出版商)”最低求助积分说明 802565