Abstract The effect of O 2 on crevice corrosion of N80 carbon steel in acidic NaCl solution is investigated. Crevice corrosion of N80 carbon steel could be initiated with or without O 2 in acidic NaCl solution. A deep corrosion groove could be formed near the crevice mouth after crevice corrosion. The crevice corrosion of N80 carbon steel is ascribed to the increased pH inside the crevice in acidic NaCl solution. The presence of O 2 in the solution could enhance the cathodic reaction processes outside the crevice, but it is not significant for the cathodic reaction processes inside the crevice. The galvanic corrosion effect between inner and outer steels could be enhanced by O 2 and then promote crevice corrosion.