Nb2O5 as a radical modulator during oxidative dehydrogenation and as a Lewis acid promoter in CO2 assisted dehydrogenation of octane over confined 2D engineered NiO–Nb2O5–Al2O3

Ordered mesoporous 2D NiO–Nb₂O₅–Al₂O₃ nano-composites were used for CO₂ assisted dehydrogenation of n-octane; and the close proximity of Ni and Nb₂O₅ in the optimised catalyst promoted CO₂ dissociation and substantially prolonged alkane activation.