Photocatalytic degradation of cefoxitin sodium antibiotic using novel BN/CdAl2O4 composite

光催化 材料科学 水溶液 复合数 降级(电信) 吸附 化学工程 核化学 复合材料 化学 催化作用 有机化学 电信 计算机科学 工程类
作者
Rajeev Kumar,M.A. Barakat,Bandar A. Al‐Mur,Fathia A. Alseroury,Jamiu O. Eniola
出处
期刊:Journal of Cleaner Production [Elsevier BV]
卷期号:246: 119076-119076 被引量:64
标识
DOI:10.1016/j.jclepro.2019.119076
摘要

The presence of the antibiotics in wastewater and drinking water is of growing concern worldwide, thereby an advanced sustainable technology needs to be developed to decontaminate the antibiotics from water resources. Herein, a series of novel boron nitrile/cadmium aluminate (BN/CdAl2O4) composites photocatalysts were synthesized by using hydrothermal methodology. Thus synthesized BN/CdAl2O4 composites were tested for the photocatalytic degradation of cefoxitin sodium (CFT) antibiotic in aqueous solution. The spectroscopic analysis confirmed that the morphology, N2 adsorption-desorption, and optical properties of the composites changes as the amount of the BN varies in BN/CdAl2O4 composite. The resulting BN/CdAl2O4 composite with a fraction of 0.2 g BN showed most efficient photocatalytic properties than the pure BN, CdAl2O4 and other BN/CdAl2O4 composites owing to its better light-harvesting properties, higher surface area, and better charge separation properties. The results revealed that the solution pH, irradiation times, and initial CFT concentration in solution controls the photocatalytic process and almost 100% CFT degradation was observed at 15 mg/L concentration within 240 min at pH 7. The results of free radicals scavenging experiments demonstrated that both positive hole and •OH free radical play dominant roles in CFT degradation. The kinetic modeling of CFT photocatalysis process showed better fitting with the first-order kinetic model as compared to the zero-order and second-order kinetic models. This study revealed that BN-0.2/CdAl2O4 composite has better CFT degradation efficiency and excellent recyclability.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
刚刚
Accept完成签到,获得积分0
1秒前
2秒前
油个大饼呜呜呜完成签到,获得积分10
3秒前
王哥完成签到,获得积分10
4秒前
诚心代芙完成签到 ,获得积分10
4秒前
4秒前
cowboy007发布了新的文献求助10
5秒前
乐乐应助eternity136采纳,获得10
6秒前
量子星尘发布了新的文献求助10
6秒前
7秒前
明眸完成签到 ,获得积分10
7秒前
8秒前
王手发布了新的文献求助10
9秒前
9秒前
9秒前
烟花应助zzq778采纳,获得10
11秒前
11秒前
欣欣发布了新的文献求助10
11秒前
小欣6116发布了新的文献求助10
12秒前
Jiuhui发布了新的文献求助10
12秒前
御风甜咖啡完成签到,获得积分10
12秒前
uupp完成签到,获得积分10
13秒前
机智雁凡完成签到,获得积分10
14秒前
Cheung2121发布了新的文献求助30
15秒前
16秒前
18秒前
谜记完成签到,获得积分10
18秒前
共享精神应助Cheung2121采纳,获得30
18秒前
光撒盐完成签到,获得积分10
19秒前
cowboy007完成签到,获得积分10
19秒前
张振宇完成签到 ,获得积分10
20秒前
zz发布了新的文献求助10
21秒前
zzq778发布了新的文献求助10
23秒前
黄怡婷完成签到 ,获得积分10
23秒前
Daisy应助科研通管家采纳,获得10
24秒前
机智苗应助科研通管家采纳,获得10
24秒前
香蕉觅云应助科研通管家采纳,获得10
24秒前
FashionBoy应助科研通管家采纳,获得10
24秒前
赘婿应助科研通管家采纳,获得10
24秒前
高分求助中
【提示信息,请勿应助】关于scihub 10000
Les Mantodea de Guyane: Insecta, Polyneoptera [The Mantids of French Guiana] 3000
徐淮辽南地区新元古代叠层石及生物地层 3000
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
Global Eyelash Assessment scale (GEA) 1000
Picture Books with Same-sex Parented Families: Unintentional Censorship 550
Research on Disturbance Rejection Control Algorithm for Aerial Operation Robots 500
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 4038368
求助须知:如何正确求助?哪些是违规求助? 3576068
关于积分的说明 11374313
捐赠科研通 3305780
什么是DOI,文献DOI怎么找? 1819322
邀请新用户注册赠送积分活动 892672
科研通“疑难数据库(出版商)”最低求助积分说明 815029