Assessment of heavy metal contamination, distribution and source identification in the sediments from the Zijiang River, China

In this study, the contents of 10 heavy metals (Sb, Cd, Cr, Mn, Co, Ni, Cu, Zn, As, and Pb) in 49 sediment samples from the Zijiang River were determined by using inductively coupled plasma-optical emission spectrometry. Contamination indexes including geoaccumulation index, modified degree of contamination, sediment quality guidelines, potential ecological risk index, together with potential ecological risk factor were used to assess heavy metal contamination in the sediments of the Zijiang River. Pearson's correlation analysis and principal component analysis were used to identify the sources of heavy metals. The results indicated that the mean values of heavy metals in the Zijiang River's sediments were found to be significantly higher than the corresponding background values. But when comparing with that in other rivers in the world, they were at medium levels except for Sb. Furthermore, a comparison of the heavy metal concentrations and the consensus-based sediment quality guidelines showed that the heavy metal pollutions (Cd, Cr, Ni, Cu, Zn, As, and Pb) tended to occasionally pose harmful impacts on the ecosystem. The values of contamination indexes revealed that serious heavy metal contamination and relatively high potential ecological risks were mainly existed in the downstream of antimony mining and smelting factories (S23–S49). In addition, high potential ecological risks of Sb were observed in sampling sites that were close to those factories (S23, S24, S25, and S27), and high potential ecological risks of Cd were observed in the downstream (S37–S49). Basing on the Pearson's correlation analysis and principal component analysis, three main sources were identified. Co, Zn, Cd, and Cu contaminants were mainly derived from agricultural activities; As, Sb, Mn, and Pb mainly came from mining and smelting activities; Cr and Ni were mainly from natural sources.