化学
铟
有机合成
化学选择性
试剂
有机反应
有机化学
水介质
醛
功能群
水溶液
组合化学
催化作用
聚合物
作者
Yang Ming,Shiwei Wang,Yi Long
标识
DOI:10.2174/1385272820666160721155937
摘要
During the last decades, indium chemistry has attracted considerable attentions from synthetic community and has found widespread applications in organic synthesis. Compared to many other commonly used metals (such as Li, Al, Mg, and Zn), indium is insensitive to water and air, allowing the operation of indium-mediated organic transformations in aqueous media. In addition, its mildness also permits indium-mediated reactions to proceed with better functional group tolerance and sometimes better chemoselectivity. In this review, a wide variety of the applications of indium in organic synthesis are summarized, with a special emphasis on reactions which have been reported recently, such as allylation reaction, alkylation reaction, cross-dehydrogenative coupling (CDC), aldehyde and enone cross-coupling reaction, Prins-type cyclization, radical cyclization, propargylation/allenylation of imines, and Diels-Alder reaction. Keywords: Indium, organoindium reagent, aqueous media, organic synthesis.
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