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Experimental study on methane explosion suppression by heptafluoropropane drived modified ABC powder

甲烷 结块 热解 材料科学 化学工程 爆炸物 化学 废物管理 复合材料 有机化学 工程类
作者
Hong Ji,Renjie Lu,Ke Yang,Juncheng Jiang,Zhixiang Xing,Jie Guo
出处
期刊:Chemical Engineering Research & Design [Elsevier BV]
卷期号:170: 623-635 被引量:29
标识
DOI:10.1016/j.psep.2022.12.031
摘要

The accidental methane explosion accident will not only pose a serious threat to the safety of industrial processes, but also cause serious environmental pollution with excessive carbon emissions and greenhouse effect. Therefore, this paper has studied the inhibition effect of modified ABC powder driven by heptafluoropropane on methane explosion. Multiple methane explosion suppression experiments were carried out using a 3.2 L horizontal experimental pipeline under various working condition. The experimental results demonstrate that the modified ABC powder has a certain inhibitory effect on methane explosions, but the explosive suppression effect of the powder improves when heptafluoropropane is used as the driving gas. When 3∼4 % heptafluoropropane is used as the driving gas, the flame is obviously inhibited. The deformation degree of flame shape is the largest at 4 % concentration. The flame totally folds inward at this point, forming an uneven finger flame. When 4 % concentration of heptafluoropropane drives the powder, there is a critical value of the concentration of the powder, which is 0.06 g/L. According to the characterization results, the average particle size of the modified ABC powder is less than 5 µm. It has good dispersibility and pyrolysis effect and is not easy to agglomerate. Under the driving action of heptafluoropropane, the powder will form aerosol, which can fully contact and react with the flame. The inert gas around the powder will reduce the forward speed of the flame and ensure that the flame and powder can fully contact and react. The combination of the two has a good synergistic effect and can effectively inhibit methane explosion.

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