Development and characterization of active starch-based films incorporating graphene/polydopamine/Cu2+ nanocomposite fillers

With increasing environmental awareness and food safety concern worldwide, biodegradable active food packaging gained wide attention in recent years. Starch has been regarded as one of the most potential biomaterials to produce biodegradable films. However, relatively poor functional performance of starch-based films severely limits their application as food packaging materials. Carbon-based fillers can be used to enhance the functional attributes of starch-based films, but they are often difficult to incorporate because of their poor matrix dispersibility. In this study, we developed a simple green method to improve the dispersity of graphene in starch-based films by modifying the graphene surfaces using mussel-inspired polydopamine and copper ions. Spectroscopy and morphology analyses showed the surface of graphene was successfully modified. The addition of the nanocomposites positively influenced the microstructure of the starch-based films, as well as impacting their mechanical, barrier, and thermal properties. Additionally, the composite films exhibited antibacterial activity against food borne pathogens, suggesting promising potential of the films acting as active food packaging. Overall, the method developed in this study has the potential for optimizing and endowing extra properties of starch-based films so as to increase their application in biodegradable food packaging.