材料科学
卤化物
钙钛矿(结构)
锡
光电子学
铅(地质)
发光二极管
二极管
量子效率
无机化学
化学工程
冶金
地貌学
地质学
工程类
化学
作者
Jiale Chen,Jiaxiong Li,Riccardo Pau,Lijun Chen,Małgorzata Kot,Han Wang,Lorenzo Di Mario,Giuseppe Portale,Maria Antonietta Loi
标识
DOI:10.1002/adma.202415958
摘要
Abstract In recent years, metal halide perovskite‐based light‐emitting diodes (LEDs) have garnered significant attention as they display high quantum efficiency, good spectral tunability, and are expected to have low processing costs. When the peak emission wavelength is beyond 900 nm the interest is even higher because of the critical importance of this wavelength for biomedical imaging, night vision, and sensing. However, many challenges persist in fabricating these high‐performance NIR LEDs, particularly for wavelengths above 950 nm, which appear to be limited by low radiance and poor stability. In this study, 3‐(aminomethyl) piperidinium (3‐AMP) is employed as a bulk additive for a tin‐lead halide perovskite. The 3‐AMP passivated films exhibit a significantly longer carrier lifetime of over 1 µs compared to neat films (0.43 µs) or to those passivated with a perfluorinated aromatic mono‐ammonium molecule (0.41 µs). Our optimized tin‐lead halide perovskite‐based LEDs show a single emission peak at 988 nm and an external quantum efficiency (EQE) of ≈1.4%.
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