共聚物
苯乙烯
马来酸酐
高分子化学
甲苯
玻璃化转变
路易斯酸
化学
材料科学
有机化学
聚合物
催化作用
作者
Shihui Li,Ling Cai,Dongmei Cui
标识
DOI:10.1002/asia.202201079
摘要
Abstract Synthesis of maleic anhydride (MA) and styrene (St) copolymers possessing ultra‐high molecular weight, strictly alternating regularity and high glass transition temperature simultaneously is still an issure with great challenge. Herein, the spontaneous alternating copolymerization of MA and St derivatives were investigated by using various Lewis acids. In the presence of alkyl aluminum or butyl magnesium, the MA−St alternating copolymers with ultra‐high molecular weight ( M n ≤166.5×10 4 ) and high glass transition temperature (211 °C≤ T g ≤216 °C) were produced and the microstructure of MA−St copolymers were analyzed by 1 H and 13 C NMR spectra. The copolymerizations of MA with St derivatives, including divinylbenzene, p ‐butenyl styrene, p ‐methoxystyrene, trans ‐anethole, p ‐fluorostyrene and p ‐chlorostyrene, also were explored by using AlOctyl 3 as an activator in toluene at 50 °C.
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