Two-dimensional manganese-iron bimetallic MOF-74 for electro-Fenton degradation of sulfamethoxazole

This study reported a novel application of Mn0.67Fe0.33-MOF-74 with two-dimensional (2D) morphology grown on carbon felt as a cathode for efficiently removing antibiotic sulfamethoxazole in the heterogeneous electro-Fenton system. Characterization demonstrated the successful synthesis of bimetallic MOF-74 by a simple one-step method. Electrochemical detection showed that the second metal addition and morphological change improved the electrochemical activity of the electrode and contributed to pollutant degradation. At pH 3 and 30 mA of current, the degradation efficiency of SMX reached 96% with 12.09 mg L-1 H2O2 and 0.21 mM ·OH detected in the system after 90 min. During the reaction, electron transfer between ≡FeII/III and ≡MnII/III promoted divalent metal ions regeneration, which ensured the continuation of the Fenton reaction. Two-dimensional structures exposed more active sites favoring ·OH production. The pathway of sulfamethoxazole degradation and the reaction mechanisms were proposed based on the intermediates identification by LC-MS and radical capture results. High degradation rates were still observed in tap and river water, revealing the potential of Mn0.67Fe0.33-MOF-74@CF for practical applications. This study provides a simple MOF-based cathode synthesis method, which enhances our understanding of constructing efficient electrocatalytic cathodes based on morphological design and multi-metal strategies.