吸附
磷酸盐
废水
化学
介孔材料
朗缪尔吸附模型
化学工程
无机化学
环境工程
环境科学
催化作用
有机化学
工程类
作者
Xuzhi Shi,Baoguo Yang,Dayi Qian,Dong Cui,Hongbin Li,Chao Wang,Yuhao Zhu,Tao Yu
出处
期刊:Separations
[MDPI AG]
日期:2024-06-11
卷期号:11 (6): 182-182
标识
DOI:10.3390/separations11060182
摘要
This study investigates the efficacy of a novel low-cost phosphate adsorbent, denoted as SH-CGCS, derived from coal gasification coarse slag (CGCS) via an alkali activation method. SH-CGCS is a mesoporous material with a specific surface area (64 m2/g) approximately six times larger than CGCS (11 m2/g), which enhances its adsorption capacity compared with CGCS. Furthermore, SH-CGCS achieves a phosphate adsorption capacity of 38.5 mg/g in strongly acidic water (pH 3) and demonstrates robust acid resistance, which makes it particularly effective for phosphate removal from acidic wastewater. Results from coexisting anion experiments affirm the good adsorption selectivity of SH-CGCS for phosphate. Moreover, SH-CGCS exhibits proficiency in treating water containing low phosphate concentrations under flowing conditions. The maximum phosphate adsorption capacity of SH-CGCS calculated using the Langmuir model is 23.92 mg/g, surpassing that of other reported adsorbents. Importantly, saturated SH-CGCS can be regenerated and reused, which contributes to its practical applicability. The adsorption mechanisms of SH-CGCS for phosphate involve ligand exchange, inner-sphere complexation, surface precipitation, and electrostatic adsorption. Thus, this study not only enhances the overall utility of CGCS but also presents a simple and efficient method for removing phosphate. Our findings indicate that SH-CGCS holds considerable potential as a phosphate adsorbent, offering a promising solution for wastewater treatment.
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