光催化
辐照
表征(材料科学)
可见光谱
材料科学
光化学
核化学
化学工程
催化作用
化学
光电子学
纳米技术
物理
有机化学
核物理学
工程类
作者
TORKIA BOUMETHRED,Hadj Benhebal,OUARDIA SEBBAH,Samir Kadi,Julien G. Mahy,Stéphanie Lambert
标识
DOI:10.1142/s0218625x25500131
摘要
In order to reduce the enormous costs of photocatalytic processes, the development of new photocatalysts sensitive to visible light constitutes a promising strategy to boost the efficiency of this method in water treatment. In this paper, strontium cobaltite nanoparticles (SrCo 2 O 4 NPs) were shaped by simple, ecological and economical methods using cobalt and strontium nitrates as precursor and freshly isolated chicken egg white as capping agents. The crystalline product SrCo 2 O 4 NPs was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and Ultraviolet–Visible (UV–Vis) spectroscopy studies. The SrCo 2 O 4 -catalyzed Congo red (CR) degradation under visible light is investigated. XRD analysis showed that the sample was indeed crystallized in the cubic spinel structure (space group Fd3m). The average size of the nanoparticles was estimated to be ∼28[Formula: see text]nm. The FT-IR spectrum shows two bands at 620 and 573[Formula: see text][Formula: see text], which are characteristic of the spinel strontium cobaltite crystalline structure. The two optical band gap energy of synthesized photocatalyst estimated from UV–Visible spectrum is 2.07 and 3.48[Formula: see text]eV. The developed photocatalyst exhibits significant photocatalytic degradation of RC in an acidic medium with 97% of the dye mineralized after 5[Formula: see text]h.
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