材料科学
极限(数学)
辐射传输
光子
工程物理
纳米技术
光学
物理
数学分析
数学
作者
Haofeng Zheng,Qi Liu,Yanlong Wang,Jing Hu,Dechun Zou,Shaocong Hou
标识
DOI:10.1002/adma.202405063
摘要
Photon recycling plays an important role in the light outcoupling of state-of-the-art solar cells and has been considered a necessary condition to achieve the radiative limit of open-circuit voltage (VOC) and efficiency. However, due to the impact of photon recycling on bulk and surface radiation of solar cells being overlooked, experimental demonstrations on the accuracy of existing photon recycling models are scarce and some contrary theoretical results also emerge. Here, we clarify the relationship between photon recycling and radiation processes, as well as the corresponding VOC losses of solar cells based on the principle of detailed balance. We show that weakening photon recycling is more effective to boost the device performance than enhancing it, promoting the theoretical efficiencies of solar cells, such as perovskite, Si, and GaAs, to 98.5%, 94.9%, and almost 100% of their radiative limit, respectively. Moreover, weakening photon recycling also helps to maintain higher efficiency when the internal radiative efficiency decreases, which benefits higher device stability. Our work provides an in-depth understanding of the role of photon recycling in solar cells and helps to push efficiency to a new limit. This article is protected by copyright. All rights reserved.
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