聚乙烯吡咯烷酮
静电纺丝
复合数
纳米纤维
热稳定性
光致发光
化学工程
化学
发光
高分子化学
核化学
复合材料
材料科学
聚合物
有机化学
光电子学
工程类
作者
Fatma Kuru,Mustafa Çoban,U. Erkarslan,Adem Dönmez,Görkem Oylumluoğlu,Muhíttín Aygün,Hülya Kara
出处
期刊:Polyhedron
[Elsevier]
日期:2023-09-01
卷期号:242: 116492-116492
标识
DOI:10.1016/j.poly.2023.116492
摘要
Two new Holmium3+ and Ytterbium3+ compounds, {Ho(4cba)3(phen)(H2O)} (1) and {Yb(4cba)3(phen)} (2) (4cba = 4-Cyanobenzoic acid, phen = 1,10-Phenanthroline) were synthesized. These compounds were then incorporated into a Polyvinylpyrrolidone (PVP) matrix at different concentrations (5 wt% to 25 wt%) using an electrospinning technique, resulting in the formation of 1D luminescent composite fibers, Ho@PVP and Yb@PVP. The products were analyzed using various characterization techniques to determine their structures and morphologies. A comprehensive study was conducted to investigate the thermal and photoluminescence properties of these composite nanofibers in comparison to their pure compounds. The findings revealed significant enhancements in the photostability and thermal stability of the composite nanofibers due to the solid environment provided by PVP for the compounds. Furthermore, it was observed that the composite nanofibers exhibited notably superior the thermal-stability and the photo-stability when compared to their pure compounds.
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