MXene‐CeO2@PDA Synergistically Enhanced Anticorrosion of Waterborne Epoxy Coating

Abstract Developing ecofriendly anticorrosion coating has great demand for marine protection. Incorporation of nontoxic inorganic fillers into waterborne epoxy (WEP) coating shows tremendous potential for enhancing corrosion resistance. However, the application of MXene/WEP coating is limited by the poor dispersion of MXene in WEP and insufficient corrosion resistance. Herein, a polydopamine (PDA) modified MXene‐CeO 2 @PDA (MCP) filler is constructed by a combination of CeO 2 with MXene and embedded into WEP to form ecofriendly anticorrosion MCP/WEP coating. Dispersion of MXene in WEP is improved by the introduction of CeO 2 and PDA modification. Benefiting from the synergy of the physical labyrinth effect of MXene and the chemical inhibition effect of CeO 2 , MCP/WEP coating exhibits remarkable anticorrosion behavior in 3.5 wt% NaCl solution with a low corrosion rate (CR) of 4.48 × 10 −6 mpy, which is three orders of magnitude lower than that of blank WEP (4.78 × 10 −3 mpy). Moreover, MCP/WEP presents long‐term and stable corrosion protection for over 30 days. The results reveal the incorporation of MCP significantly promotes the anticorrosion performance of WEP.