The Influence of Cu on the Microstructure and Properties of TC4/Q345 High-entropy Joints by Laser Welding

FeCoNiCrCu high-entropy alloy (HEA) and Cu foils were utilized as the intermediate layer to conduct laser welding of TC4 titanium alloy and Q345 steel. Welding is performed by adding single HEA and Cu/HEA double foils as interlayer respectively. We conducted in-depth studies on the microstructure and mechanical properties of the joint by stereomicroscopy, metallographic microscope, scanning electron microscope (SEM), micro-area X-ray diffraction (XRD), nanoindentation, electron backscatter diffraction (EBSD), and tensile testing. The results indicate that the position of the copper foil significantly affects the microstructure and performance of the joint. When the copper foil is on the TC4 side, its lower melting point causes a deeper keyhole, resulting in a narrower weld bead and then reduced content of Fe and Ti in the weld. Simultaneously, the increased proportion of Cu in the weld significantly enhances the content of Cu-rich phases. In the weld zone, we observed freely distributed Cu-rich phases and Ti-rich phases generated along the interface. Under tensile loads, cracks primarily initiate and propagate along the Cu-rich phases, leading to typical delamination on the fracture surface. With the copper foil on the TC4 side, due to the increased copper content in the microstructure, the hardness of the interface between the titanium alloy and the weld decreases, while the joint exhibits the highest tensile strength, reaching a maximum of 417 MPa.