Mechanistic studies on Cu(NO3)2/TEMPO-catalyzed aerobic oxidation of alcohols to carboxylic acids
化学
酒精氧化
催化作用
有机化学
作者
NULL AUTHOR_ID,NULL AUTHOR_ID,NULL AUTHOR_ID,NULL AUTHOR_ID,Hui Qian,Shengming Ma
出处
期刊：Organic chemistry frontiers [The Royal Society of Chemistry] 日期：2024-01-01卷期号：11 (18): 5003-5009
标识
DOI：10.1039/d4qo00791c
摘要
A mechanism involving a Cu(NO 3 ) 2 –TEMPO adduct as identified by SAESI-MS studies for the Cu-catalyzed aerobic oxidation of alcohols to carboxylic acids is proposed, which is supported by experimental studies and DFT calculations.
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