Long-term removal of perfluoroalkyl substances via activated carbon process for general advanced treatment purposes

活性炭 化学 流出物 吸附 粉末活性炭处理 水处理 解吸 环境化学 碳纤维 气味 环境工程 有机化学 环境科学 复合数 复合材料 材料科学
作者
Yoshifumi Nakazawa,Koji Kosaka,Nobue Yoshida,Mari Asami,Yoshihiko Matsui
出处
期刊:Water Research [Elsevier BV]
卷期号:245: 120559-120559 被引量:9
标识
DOI:10.1016/j.watres.2023.120559
摘要

Granular or powdered activated carbon (GAC/PAC) processes are installed in full-scale drinking water treatment plants (DWTPs) to reduce disinfection byproduct precursors, odor, ammonia, and pesticides. This study investigated the ability of GAC/PAC processes in 23 DWTPs to remove per- and polyfluoroalkyl substances (PFASs). In the GAC process, filter breakthrough of perfluoroalkyl carboxylic acids (PFCAs) occurred faster as the PFCA chain length is decreased. During periods of high water temperatures (20-29 °C), the effluent concentration of two short-chain PFCAs (C4 and C5) surpassed that of the influent after the throughput reached 5,000-7,500 bed volumes (equivalent to 2-3 months) due to desorption. However, such desorption was not observed during periods of low water temperatures (5-19 °C). Meanwhile, long-chain PFCAs were consistently removed, as the GAC was replaced before breakthrough became noticeable. PFAS removal deteriorated at a remarkably fast rate after a partial breakthrough of several tens of percent. Biological activated carbon was proved ineffective in removing PFASs due to its diminished adsorption capacity after long-term use. The PAC process, however, exhibited a slight decrease in PFCA residual (10%) at higher water temperatures (15-30 °C). The PAC dose required for a certain residual ratio was lower with an increase in the hydrophobicity of PFAS; C8-PFCA only required 20 mg/L of PAC for 50% removal, while C4-PFCA required a significantly higher dose of 100-700 mg/L. Consequently, the activated carbon process, which removes organic contaminants in surface water, was inadequate in removing PFASs, particularly those with short chains. Thus, it is recommended that GAC filters be replaced more frequently (within two months) for short-chain PFAS removal. Further, the adsorption performance of PAC must be enhanced.
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