Fabrication of biodegradable films with UV-blocking and high-strength properties from spent coffee grounds

Utilizing spent coffee grounds (SCG) to produce high value-added materials is attractive and meaningful. In this work, a multi-functional biomass film is prepared from SCG and dissolving pulp through a dissolution and regeneration process. Importantly, dissolving pulp as a reinforcing additive can significantly enhance the mechanical strength of the regenerated SCG film. The prepared composite films with SCG contents ranging from 33.33 wt% to 81.82 wt% demonstrate excellent optical and mechanical properties. The composite film with 66.67 wt% SCG exhibits outstanding UV blocking capability (99.43 % for UVB and 96.59 % for UVA) and high haze (69.22%); meanwhile, the composite film with 33.33 wt% SCG performs better mechanical strength (58.69 MPa tensile strength and 3.13 GPa Young's modulus) and superior biodegradability (fully degraded within 26 days by being buried in soil) than commercial plastic. This work generally introduces a facile and practical approach to converting waste SCG into promising materials in various fields.