MOF-derived Co-Ni layered double hydroxides/polyethyleneimine modified chitosan micro-nanoreactor for high-efficiency capture of uranium from seawater

The preparation of powder adsorbent into microsphere adsorbent is one of the effective methods for the industrialization of uranium extraction from seawater. Herein, a MOF-derived Co-Ni layered double hydroxides/polyethyleneimine modified chitosan micro-nanoreactor (DNPM) was prepared by a simple method in this work. The microstructure and chemical structure of DNPM were comprehensively characterized. The pH value, adsorption time, initial solution concentration, temperature, competitive ions, regeneration performance, and bed column heights were investigated for the adsorption performance of DNPM by batch adsorption and fixed-bed column continuous adsorption experiments. When the contact time was 8 h, the initial concentration was 150 mg/L, and the pH value was 6, the adsorption capacity of DNPM was 334.67 mg/g. The uranium adsorption by DNPM fits with the pseudo-second-order kinetic and Langmuir models, which was a spontaneous and endothermic process. In addition, DNPM has good adsorption selectivity and reusability. The fixed-bed column continuous adsorption experiment shows that the adsorption capacity increased with the increase of bed column height. The adsorption mechanism can be attributed to coordination chelation and electrostatic interaction. In general, this work provides an effective strategy for developing environmentally friendly uranium adsorbent that can be industrially used.