Abundant oxygen vacancies constructed by deep reduction strategy to achieve ultra-high peroxomonosulfate activation efficiency for degrading organic pollutions in water

Herein, peroxymonosulfate (PMS)-like Fenton oxidation catalyst (DR-Vo-Co 3 O 4 ) with rich oxygen vacancies and carved flower-like structures were constructed using Co 3 O 4 as precursor via deep reduction strategy. DR-Vo-Co 3 O 4 could activate PMS to achieve almost 100% degradation of sulfadiazine (SD) within 1 min with ultra-high efficiency, possessing a degradation rate constant ( k ) value as high as 5.9±0.2 min -1 , which was 86 and 5 times higher than the unreduced and reported maximum, respectively. Furthermore, the catalytic system showed unparalleled reactivity towards 14 different types of contaminants, with the maximum k value even exceeding 20 min -1 . The carved flower-like structure of DR-Vo-Co 3 O 4 catalysts not only facilitated PMS adsorption, but also provided more reaction sites for PMS activation. Meanwhile, rich oxygen vacancies could effectively tune the DR-Vo-Co 3 O 4 surface electronic state to further accelerate charge transfer, significantly enhancing PMS oxidation efficiency. Catalytic mechanism analysis revealed that 1 O 2 and O 2 •− played a dominant role in contaminant degradation. • Ultra-high active PMS-like Fenton catalysts was prepared via deep reduction strategy. • DR-Vo-Co 3 O 4 +PMS system own outstanding rate constant of 5.9±0.2 min -1 for sulfadiazine. • DR-Vo-Co 3 O 4 +PMS system has excellent versatility for 14 different types of contaminants. • Rich Vo accelerated charge transfer, greatly enhancing PMS activation efficiency.