分子间力
胶粘剂
超分子化学
粘附
铂金
分子
材料科学
高分子化学
化学
纳米技术
化学工程
复合材料
有机化学
催化作用
工程类
图层(电子)
作者
Zhao Wang,Kang Huang,Xizi Wan,Mingqian Liu,Yong Chen,Xinghua Shi,Shutao Wang
标识
DOI:10.1002/anie.202211495
摘要
Surface adhesion has a great contradiction in high strength and good reversibility given their mutually exclusive requirements of fixed crosslinked networks and dynamic chain motion. Herein, we demonstrate a supramolecular organoplatinum(II) adhesive system regulated by intermolecular PtII ⋅⋅⋅PtII interactions that can simultaneously achieve high-strength and excellent reversible adhesion to various substrates. Upon alternating temperature, the assembly of suitably substituted organoplatinum(II) molecules can switch between well-ordered and disordered states via tuning PtII ⋅⋅⋅PtII interactions, resulting in stable reversible adhesion even after 100 cycles with a robust strength of ≈1.25 MPa and a large on-off ratio of ≈25. Along with the switch of PtII ⋅⋅⋅PtII contacts, the surface adhesion of organoplatinum(II) adhesives can be monitored by their changes in electrical signals. This study will open up new inspirations for developing high-performance reversible adhesives.
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