Elucidating Organic Reaction Mechanisms Using Photo-CIDNP Spectroscopy

CIDNP (chemically induced dynamic nuclear polarization) arises in radical pairs or biradicals but is detected in the diamagnetic reaction products. Hence, it can be used not only to identify and characterize both types of species but also to establish the pathways connecting precursors, paramagnetic intermediates and products, and to employ the polarizations as labels to individual nuclei. Recent applications of CIDNP to elucidate the mechanisms of photochemical reactions are reviewed, which illustrate all these facets.