苝
二亚胺
非共价相互作用
平面的
螺旋桨
化学
聚合物
有机太阳能电池
光化学
材料科学
分子
纳米技术
有机化学
工程类
计算机科学
氢键
计算机图形学(图像)
海洋工程
作者
Min Deng,Guangjun Zhang,Liyang Yu,Xiaopeng Xu,Qiang Peng
标识
DOI:10.1016/j.cej.2021.131910
摘要
• Planar propeller-like PDIs were synthesized by noncovalent interactions. • Thiophene and nitrogen annulations were applied to PDI arms with increasing photovoltaic property. • Fine tuning the noncovalent interaction strength promoted PCEs reaching 10.52%. The development of non-fullerene small molecule acceptors enabled fast increasing top power conversion efficiency of polymer solar cells (PSCs). Perylene diimide (PDI) derivatives are among the most promising non-fullerene small molecule acceptors for their relatively straightforward accessible PDI chromophores readily deliver high electron mobility and intensive photon absorption in visible range. In this work, we demonstrated noncovalent interaction as a third strategy of connecting the PDI arms to the center core of propeller-like PDI derivatives other than flexible and all fused linkages through designing and synthesizing two novel PDI derivatives. Thiophene-annulated PDI arms were connected to a small electron withdrawing 1,3,5-triazine center core where N⋯S noncovalent conformational locks restricted the distortion of molecules. Fine tuning of the aggregation tendency of the PDI derivative by introducing N-annulation at the outer bay position of each PDI arms which achieved an outstanding power conversion efficiency reaching 10.52%, which is one of the top PCEs of PDI-based PSCs.
科研通智能强力驱动
Strongly Powered by AbleSci AI