In this work, through analysis of excition distribution mechanism, the multiple‐sensitizing process red hyperfluorescence top–emission device achieved unprecedent high current efficiency of 53.6 cd/A with CIE (0.666, 0.334), LT95 of 900 hrs and low voltage of 4.15 V at current density of 15mA/cm 2 among the reported Hyperfluorescence OLEDs.