Stabilization of arsenic and antimony Co-contaminated soil with an iron-based stabilizer: Assessment of strength, leaching and hydraulic properties and immobilization mechanisms

Soils with relatively high concentrations of arsenic (As) and antimony (Sb) in mining areas would impose significant risks to human health and ecosystem. A new stabilizer PFSC composed of polymerized ferric sulfate (PFS) and calcium hydroxide (Ca(OH)2) is proposed to stabilize the soil with co-existed As and Sb sampled at an abandoned arsenic factory site. The effects of stabilizer dosage on the properties of the stabilized soil including leached concentrations of As and Sb, unconfined compressive strength (UCS), and hydraulic conductivity (kw) were investigated. The mechanisms of As and Sb immobilization in the soils were interpreted by Tessier's sequential extraction procedure (SEP), scanning electron microscope (SEM), and X-ray diffraction (XRD) results. The results showed increasing PFSC dosage was effective for reducing leached concentrations of As and Sb. When the PFSC dosage increased from 2% to 10%, the UCS and kw increased from 84 to 206 kPa and decreased from 6.48 × 10-8 to 6.33 × 10-9 m s-1, respectively. Tessier's SEP results showed that the leachable As and Sb fractions decreased from 12% to 5.6% and 7.5% to 3.8%, while the Fe-Mn oxides bound fractions increased from 22.3% to 29.4% and 13.2% to 19.5%. The SEM images and XRD patterns of untreated and PFSC stabilized contaminated soils indicated that hematite and calcite (CaCO3) were the main products of PFSC stabilization processes. Adsorption on ferrihydrite, entrapment in hematite lattices, and co-precipitate with calcite might were the main mechanisms of As and Sb immobilization.