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Coaxial laser cladding of cobalt-base alloy StelliteTM 6 on gray cast iron/investigations on friction, wear versus commercial brake pad, and corrosion characteristics

钨铬钴合金 材料科学 腐蚀 冶金 铸铁 微观结构 摩擦学 灰铸铁 合金 复合材料
作者
Maximilian Kiehl,Adriano Scheid,Karin Graf,Benedikt Ernst,Ulrich Tetzlaff
出处
期刊:Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering [SAGE]
卷期号:237 (14): 3285-3303 被引量:4
标识
DOI:10.1177/09544070221145512
摘要

Environmental legislation and the electrification of vehicles place increased requirements on brake disks in terms of wear and corrosion resistance. Departing from a preliminary study, the present investigation examined the friction and wear behavior as well as the corrosion properties of Stellite™ 6 coatings on gray cast iron, which were deposited by laser cladding. The friction and wear experiments were conducted on a pin-on-disk tribometer at contact pressures of 1.0 and 2.0 MPa as well as rotation speeds of 0.2, 0.4, 0.6, 0.8, and 2.0 m/s. The pins are manufactured from an automotive semi-metallic brake pad. The friction behavior of gray cast iron and Stellite™ 6 coatings is similar under changing test conditions. The tribological behavior is strongly influenced by the microstructural and mechanical properties of the coatings and the brake pad material. A third body layer of contact patches is formed on Stellite™ 6, which mainly consists of brake pad components. The transformation of the Co-matrix (fcc → hcp), subsurface fatigue, and tribo-oxidation are the main wear mechanism for Stellite™ 6. The electrochemical characteristics were analyzed by potentiodynamic polarization, and the corrosion rate was determined with Tafel plots in 3.5% NaCl solution, respectively. Compared to gray cast iron, Stellite™ 6 coatings have a pronounced corrosion resistance due to the formation of a protective passive layer of Co and Cr oxides. This corrosion resistance is mainly influenced by the microstructure. The corrosion rate of the coatings increases in parallel with the Fe dilution.
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