块(置换群论)
化学
组合化学
材料科学
计算机科学
化学工程
数学
工程类
组合数学
作者
Somdatta Ghosh Dey,M. L. Aggarwal,Debsena Chakraborty,Partha Sarathi Mukherjee
摘要
Metal-organic self-assembly with flexible moieties is a budding field of research due to the possibility of the formation of unique architectures. Tetrazole, characterised by four nitrogen atoms in a five-member ring, exhibits immense potential as a component. Tetrazole offers four coordination sites for binding to the metal centre with nine distinct binding modes, leading to various assemblies. This review highlights different polymeric and discrete tetrazole-based assemblies and their functions. The meticulous manipulation of stoichiometry, ligands, and metal ions required for constructing discrete assemblies has also been discussed. The different applications of these architectures in separation, catalysis and detection have also been accentuated. The latter section of the review consolidates tetrazole-based cage composites, highlighting their applications in cell imaging and photocatalytic applications.
科研通智能强力驱动
Strongly Powered by AbleSci AI