Soap Film Transfer Printing for Ultrathin Electronics

Abstract Flexible and stretchable electronics have attractive applications inaccessible to conventional rigid electronics. However, the mainstream transfer printing techniques have challenges for electronic films in terms of thickness and size and limitations for target substrates in terms of curvature, depth, and interfacial adhesion. Here a facile, damage‐free, and contamination‐free soap film transfer printing technique is reported that enables the wrinkle‐free transfer of ultrathin electronic films, precise alignment in a transparent manner, and conformal and adhesion‐independent printing onto various substrates, including those too topographically and adhesively challenging by existing methods. In principle, not only the pattern, resolution, and thickness of transferred films, but also the curvature, depth, and adhesion of target substrates are unlimited, while the size of transferred films can be as high as meter‐scale. To demonstrate the capabilities of soap film transfer printing, pre‐fabricated ultrathin electronics with multiple patterns, single micron resolution, sub‐micron thickness, and centimeter size are conformably integrated onto the ultrathin web, ultra‐soft cotton, DVD‐R disk with the minimum radius of curvature of 131 nm, interior cavity of Klein bottle and dandelion with ultralow adhesion. The printed ultrathin sensors show superior conformabilities and robust adhesion, leading to engineering opportunities including electrocardiogram (ECG) signal acquisition and temperature measurement in aqueous environments.