Metal–Organic Frameworks Photocatalyst Through Plasmon‐Induced Hot‐Electrons

Abstract Plasmonic metal–organic frameworks (plasmonic‐MOFs) ingeniously meld the homogeneous and vast porosity of MOFs with the distinctive plasmonic characteristics of metallic nanoparticles (NPs), creating a powerful synergy. This innovative combination is leveraged for enhanced plasmon‐induced hot‐electron photocatalysis, particularly within polystyrene beads adorned with silver nanoparticles (AgNPs) and encapsulated by zeolitic imidazolate framework‐8 (ZIF‐8). The strategic incorporation of AgNPs into this composite material generates hot carriers, significantly enhancing the catalytic performance of ZIF‐8. This approach not only exemplifies the potential for advanced photocatalytic processes of MOFs, but also paves the way for groundbreaking applications in environmental remediation and sustainable chemistry.