Non‐Stop Switching Separation of Superfine Solid/Liquid Dispersed Phases in Oil and Water Systems Using Polymer‐Assisted Framework Fiber Membranes

Fabricating filtration membranes with wide applicability and high efficiency is always a challenge in the precise separation of small colloidal particles under mild conditions. For this purpose, a strategy mixing supramolecular framework fiber with polymer is adopted. The fibrous assembly in the gel state provides uniform nanopores for both channel and interception and controlled wettability for lyophilic/lyophobic switching. The used polymer fills the gaps between fiber assemblies and improves the mechanical property. The composite membrane shows both under-oil superhydrophobic and underwater superoleophobic nature, which allows the conversions via in situ modulation of joystick solvents. Based on surface wetting and size-sieving, ultrafine hard nanoparticles dispersing in both hydrophobic organic solvents and water are selectively sieved. In addition, on-demand separation of water-in-oil and oil-in-water microemulsions without and with surfactants as systems containing soft droplets are realized. The smallest cut-off size of ≈3 nm is achieved for both hard and soft emulsions, while separation efficiency maintains during sustained in situ reversible switches.