Separator Design Strategies to Advance Rechargeable Aqueous Zinc Ion Batteries

Abstract With the increasing demand for low‐cost and high‐safety portable batteries, aqueous zinc‐ion batteries (ZIBs) have been regarded as a potential alternative to the lithium‐ion batteries, bringing about extensive research dedicated in the exploration of high‐performance and highly reversible ZIBs. Although separators are generally considered as non‐active components in conventional research on ZIBs, advanced separators designs seem to offer effective solutions to the majority of issues within ZIBs system. These issues encompass concerns related to the zinc anode, cathode, and electrolyte. Initially, we delve into the origins and implications of various inherent problems within the ZIBs system. Subsequently, we present the latest research advancements in addressing these challenges through separators engineering. This includes a comprehensive, detailed exploration of various strategies, coupled with instances of advanced characterizations to provide a more profound insight into the mechanisms that influence the separators. Finally, we undertake a multi‐criteria evaluation, based on application standards for diverse substrate separators, while proposing guiding principles for the optimal design of separators in zinc batteries. This review aims to furnish valuable guidance for the future development of advanced separators, thereby nurturing progress in the field of ZIBs.