纳米片
纳米复合材料
乙烯醇
材料科学
剥脱关节
热稳定性
热解
碳纤维
纳米技术
复合材料
复合数
化学工程
核化学
聚合物
石墨烯
化学
工程类
作者
Xiaowei Mu,Wei Cai,Yuling Xiao,Lingxin He,Xia Zhou,Huijuan Wang,Wenwen Guo,Weiyi Xing,Lei Song
标识
DOI:10.1016/j.compositesb.2020.108218
摘要
N doped carbon nanosheet and B N co-doped carbon (BNC) nanosheet are first prepared through exfoliation of carbon of Schiff based covalent organic frameworks (COFs) under ultrasound using sodium lignin sulfonate as the intercalation agent and modifier. Then poly (vinyl alcohol) (PVA)/BNC nanocomposite with enhanced thermal oxidation stability, good mechanical performances and enhanced flame retardancy has been prepared through solution blending. The temperature at 5 wt% weight loss and peak heat release rate of PVA loaded with 4 wt% of BNC nanosheet increase by 31.9 °C and 57.3% compared with that of untreated PVA, respectively. A new fire hazard evaluation system based on analytic hierarchy process (AHP) is raised to comprehensively estimate fire risk of prepared sample. It is deduced from AHP that PVA loaded with 4 wt% BNC nanosheet shows the lowest fire risk (77.9 score). The effect of BNC nanosheet on pyrolysis mode of PVA in gaseous and condensed phase has also been investigated to figure out the reason for low fire risk of treated PVA.
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