光催化
材料科学
可见光谱
热液循环
异质结
复合数
水热合成
吸收(声学)
辐照
分解水
吸收边
制氢
化学工程
纳米技术
催化作用
带隙
光电子学
复合材料
有机化学
化学
核物理学
工程类
物理
出处
期刊:Nanotechnology
[IOP Publishing]
日期:2020-09-10
卷期号:31 (50): 505711-505711
被引量:17
标识
DOI:10.1088/1361-6528/abb72c
摘要
CoIn2S4, a black semiconducting material, possesses an outstanding visible light response and is employed to modify g-C3N4. A series of CoIn2S4/g-C3N4 heterojunctional photocatalysts are synthesized via a hydrothermal method, whereby cubic CoIn2S4 nanosheets are in situ immobilized on the surfaces of porous g-C3N4 nanosheets. Compared with the pristine g-C3N4 and CoIn2S4, under visible light (λ > 420 nm) irradiation, the CoIn2S4/g-C3N4 composite samples show markedly enhanced photocatalytic activity in hydrogen evolution. Among all of the samples, the 30% CoIn2S4/g-C3N4 sample shows the maximum H2 evolution rates, 5.2 and 23.9 times higher than those of g-C3N4 and CoIn2S4, respectively. The efficient photocatalytic activity of CoIn2S4/g-C3N4 composite photocatalysts is attributed to the formation of an intimate heterostructure, which not only significantly facilitates charge migration, but also enhances visible light absorption. Moreover, a plausible photocatalytic mechanism for the composite photocatalyst has been elucidated. This research provides a novel hint for fabricating visible-light-responsive heterojunction photocatalysts with high performance for energy production.
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