Solvent Dependent Benzylic Radical Bromination of Aromatic Sulfonyl Chlorides
化学
卤化
磺酰
乙腈
甲苯
溴化物
溶剂
产量(工程)
有机化学
药物化学
烷基
冶金
材料科学
作者
Laura Quartara,Maria Maddalena Altamura,Annalisa Guerri,Rossano Nannicini,Martina Gensini,Gianluca Battaglia
出处
期刊:Letters in Organic Chemistry [Bentham Science] 日期:2006-02-13卷期号:3 (3): 191-194被引量:3
标识
DOI:10.2174/157017806775789958
摘要
We have studied the solvent dependent radical bromination of toluene sulfonyl chlorides. The use of acetonitrile allows to avoid chlorinated solvents and to improve the yield and the reproducibility of the process. Keywords: aromatic sulfonyl chloride, benzyl bromide, N-bromosuccinimide, Radical bromination