皮克林乳液
材料科学
单体
二乙烯基苯
聚合
化学工程
乳液聚合
混合材料
高分子化学
悬浮聚合
乳状液
球体
纳米颗粒
聚合物
共聚物
纳米技术
复合材料
苯乙烯
工程类
物理
天文
作者
Tao Chen,Patrick J. Colver,Stefan A. F. Bon
标识
DOI:10.1002/adma.200602447
摘要
Organic–inorganic hybrid hollow spheres are prepared by using a TiO2-stabilized Pickering emulsion polymerization method (see figure). By self-organization of TiO2 nanoparticles at the interface of oil (monomer and solvent) and water, colloidosomes are formed and used as polymerization vessels to obtain the hybrid hollow spheres. The diameter and mechanical stability can be tailored by varying the relative amount of oil phase and the relative amount of divinylbenzene (DVB) in the monomer, respectively.
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